链状聚[[(乙酸根-κ(2)O,O')[2-(4-氧代-1,4-二氢喹啉-1-基)乙酸根-κO(1)]铜(II)]-μ-4,4'-联吡啶-κ(2)N:N']
catena-Poly[[(acetato-κ(2)O,O')[2-(4-oxo-1,4-dihydro-quinolin-1-yl)acetato-κO(1)]copper(II)]-μ-4,4'-bipyridine-κ(2)N:N'].
作者信息
Wang Jun, Dai Chuntao, Nie Jianhua
机构信息
Zhongshan Polytechnic, Zhongshan, Guangdong 528404, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):m1132. doi: 10.1107/S160053681203303X. Epub 2012 Jul 28.
In the title compound, Cu(C(11)H(8)NO(3))(CH(3)COO)(C(10)H(8)N(2)), the Cu(II) ion is six-coordinated by two N atoms from two 4,4'-bipyridine ligands, four O atoms from one acetate ligand, one 2-(4-oxo-1,4-dihydro-quinolin-1-yl)acetate ligand and one water mol-ecule in a distorted octa-hedral geometry. The 4,4'-bipyridine ligands inter-connect [Cu(C(11)H(8)NO(3))(CH(3)COO)] units, giving rise to a chain along [010]. These chains are further linked to each other by O-H⋯O hydrogen bonds, leading to a two-dimensional supra-molecular network parallel to (100).
在标题化合物[Cu(C₁₁H₈NO₃)(CH₃COO)(C₁₀H₈N₂)]ₙ中，Cu(II)离子由两个4,4'-联吡啶配体的两个N原子、一个乙酸根配体的四个O原子、一个2-(4-氧代-1,4-二氢喹啉-1-基)乙酸根配体的一个O原子以及一个水分子以扭曲的八面体几何构型六配位。4,4'-联吡啶配体连接[Cu(C₁₁H₈NO₃)(CH₃COO)]单元，形成沿[010]方向的链。这些链通过O—H⋯O氢键进一步相互连接，形成平行于(100)的二维超分子网络。
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