沿取向寡聚噻吩堆积的定向层交换。
Directional stack exchange along oriented oligothiophene stacks.
机构信息
Department of Organic Chemistry, University of Geneva, Geneva, Switzerland.
出版信息
Chem Commun (Camb). 2012 Nov 7;48(86):10618-20. doi: 10.1039/c2cc35773a.
PMID:23011272
Abstract
Directional growth of π-basic oligothiophene stacks on solid substrates is achieved by self-organizing, surface-initiated disulfide exchange polymerization. Successful addition of co-axial π-acidic stacks by templated hydrazone exchange provides general access to multicomponent architectures of unique complexity.
摘要
通过自组织、表面引发的二硫键交换聚合，实现了π 基础寡聚噻吩在固体基底上的定向生长。通过模板腙交换成功添加共轴 π 酸性堆叠，为具有独特复杂性的多组分结构提供了通用途径。
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