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超声辅助大豆油制备生物柴油用 Brønsted 酸性离子液体作催化剂。

Ultrasound-assisted production of biodiesel from soybean oil using Brønsted acidic ionic liquid as catalyst.

机构信息

School of Resources and Environment, University of Jinan, Jinan 250022, Shandong Province, PR China.

出版信息

Bioresour Technol. 2012 Dec;125:332-4. doi: 10.1016/j.biortech.2012.08.132. Epub 2012 Sep 13.

Abstract

Biodiesel production from soybean oil with methanol was performed in the presence of a Brønsted acidic ionic liquid-based catalyst under ultrasound irradiation. The influences of various parameters on the transesterification reaction, including the amount of catalyst, the molar ratio of methanol to oil, the temperature and the ultrasound power, were investigated. The optimal conditions were: methanol/oil molar ratio of 9:1, 1.0 wt.% catalyst in oil, ultrasound power of 200 W, and reaction temperature of 60°C. Under these conditions, the conversion of triglycerides to fatty acid methyl esters was about 93.2% within the reaction time of 60 min.

摘要

在超声辐射下,用甲醇从大豆油中生产生物柴油,使用了一种基于 Brønsted 酸性离子液体的催化剂。考察了各种参数对酯交换反应的影响,包括催化剂用量、甲醇与油的摩尔比、温度和超声功率。优化条件为:甲醇/油摩尔比 9:1,油中催化剂用量 1.0wt.%,超声功率 200W,反应温度 60°C。在此条件下,反应 60min 时,三酸甘油酯转化为脂肪酸甲酯的转化率约为 93.2%。

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