铑或钌催化的氧化 C-H/C-H 交叉偶联：直接构建扩展的π共轭体系。
Rhodium or ruthenium-catalyzed oxidative C-H/C-H cross-coupling: direct access to extended π-conjugated systems.
机构信息
Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, Sichuan University, Chengdu, PR China.
出版信息
Angew Chem Int Ed Engl. 2013 Jan 7;52(2):580-4. doi: 10.1002/anie.201207196. Epub 2012 Nov 26.
PMID:23184621
Abstract
Doubling up: a chemo- and regioselective oxidative cross-coupling between various N-heteroarene-containing arenes and heteroarenes has been carried out by rhodium- or ruthenium-catalyzed twofold C-H activation, to deliver an array of highly functionalized π-conjugated systems.
摘要
双重交叉
通过铑或钌催化的双重 C-H 活化，实现了各种含 N-杂芳环芳烃和杂芳烃之间的化学和区域选择性氧化交叉偶联，从而构建了一系列高度功能化的π共轭体系。
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