Institut für Theoretische Physik, Universität zu Köln, Zülpicher Strasse 77, 50937 Köln, Germany.
Phys Rev Lett. 2012 Oct 26;109(17):176401. doi: 10.1103/PhysRevLett.109.176401. Epub 2012 Oct 23.
The critical properties of the finite temperature Mott end point are drastically altered by a coupling to crystal elasticity, i.e., whenever it is amenable to pressure tuning. Similar as for critical piezoelectric ferroelectrics, the Ising criticality of the electronic system is preempted by an isostructural instability, and long-range shear forces suppress microscopic fluctuations. As a result, the end point is governed by Landau criticality. Its hallmark is, thus, a breakdown of Hooke's law of elasticity with a nonlinear strain-stress relation characterized by a mean-field exponent. Based on a quantitative estimate, we predict critical elasticity to dominate the temperature range ΔT*/T(c)≃8%, close to the Mott end point of κ-(BEDT-TTF)(2)X.
有限温度莫特端点的临界性质会因与晶体弹性的耦合而发生剧烈变化,也就是说,只要能够通过压力调节来实现这种耦合。与临界压电热铁电体类似,电子系统的伊辛临界性被等结构不稳定性所取代,长程剪切力抑制了微观涨落。结果,端点受朗道临界性的支配。因此,其特征是弹性的胡克定律失效,应变-应力关系是非线性的,其特征是平均场指数。基于定量估计,我们预测临界弹性将主导温度范围ΔT*/T(c)≃8%,接近 κ-(BEDT-TTF)(2)X 的莫特端点。