（2-氨基乙烷硫醇根合-κ(2)N,S）双-[1,2-双（二苯基膦基）乙烷-κ(2)P,P']钌（II）六氟磷酸酯
(2-Amino-ethane-thiol-ato-κ(2)N,S)bis-[1,2-bis-(diphenyl-phosphan-yl)ethane-κ(2)P,P']ruthenium(II) hexa-fluoridophosphate.
作者信息
Igashira-Kamiyama Asako, Tamura Motoshi, Konno Takumi
机构信息
Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Nov 1;68(Pt 11):m1432. doi: 10.1107/S1600536812044273. Epub 2012 Oct 31.
In the crystal of the title compound, [Ru(C(2)H(6)NS)(C(26)H(24)P(2))(2)]PF(6), the Ru(II) atom is in a slightly distorted octa-hedral geometry, coordinated by one 2-amino-ethane-thiol-ate (aet) and two 1,2-bis-(diphenyl-phosphan-yl)ethane (dppe) ligands. The crystal consists of a pair of enanti-omers (Δ and Λ) of the compound. The Δ and Λ isomers have the λ and δ conformations for the aet chelate rings and the δ and λ conformations for the dppe chelate rings. The F atoms of the PF(6) (-) counter-anion are disordered over three positions, with site occupancies of 0.4, 0.3 and 0.3.
在标题化合物[Ru(C₂H₆NS)(C₂₆H₂₄P₂)₂]PF₆的晶体中，Ru(II)原子处于略微扭曲的八面体几何构型，由一个2-氨基乙硫醇盐（aet）和两个1,2-双（二苯基膦基）乙烷（dppe）配体配位。该晶体由该化合物的一对对映体（Δ和Λ）组成。Δ和Λ异构体的aet螯合环具有λ和δ构象，dppe螯合环具有δ和λ构象。PF₆⁻抗衡阴离子的F原子在三个位置上无序分布，占位率分别为0.4、0.3和0.3。
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