Intramolecular C(sp3)-N coupling by oxidation of benzylic C,N-dianions.
作者信息
Jeffrey Jenna L, Bartlett Emily S, Sarpong Richmond
机构信息
Department of Chemistry, University of California, Berkeley, Berkeley, CA 94720, USA.
出版信息
Angew Chem Int Ed Engl. 2013 Feb 18;52(8):2194-7. doi: 10.1002/anie.201209591. Epub 2013 Jan 16.
Abstract
摘要
相似文献
1
Intramolecular C(sp3)-N coupling by oxidation of benzylic C,N-dianions.通过苄基碳氮二阴离子氧化实现分子内C(sp3)-N偶联
Angew Chem Int Ed Engl. 2013 Feb 18;52(8):2194-7. doi: 10.1002/anie.201209591. Epub 2013 Jan 16.
2
N-Heterocyclic carbene-catalyzed intramolecular aldehyde-nitrile cross coupling: an easy access to 3- aminochromones.N-杂环卡宾催化的醛-腈分子内交叉偶联反应：一种构建 3-氨基色酮的简便方法。
Org Lett. 2010 Jan 15;12(2):352-5. doi: 10.1021/ol9026232.
3
Aerobic oxidative C-H olefination of cyclic N-sulfonyl ketimines catalyzed by a rhodium catalyst.铑催化的环状 N-磺酰基亚胺的有氧氧化 C-H 烯烃化反应。
Org Lett. 2014 Jun 6;16(11):3040-3. doi: 10.1021/ol501152a. Epub 2014 May 9.
4
Antioxidant Activity of Novel Fused Heterocyclic Compounds Derived from Tetrahydropyrimidine Derivative.源自四氢嘧啶衍生物的新型稠合杂环化合物的抗氧化活性
Chem Pharm Bull (Tokyo). 2015;63(11):866-72. doi: 10.1248/cpb.c15-00452.
5
Nucleophilic phosphine-catalyzed intramolecular Michael reactions of N-allylic substituted α-amino nitriles: construction of functionalized pyrrolidine rings via 5-endo-trig cyclizations.亲核膦催化的 N-烯丙基取代的α-氨基腈的分子内迈克尔反应：通过 5-endo-trig 环化构建官能化的吡咯烷环。
J Org Chem. 2014 May 16;79(10):4456-62. doi: 10.1021/jo500418s. Epub 2014 May 5.
6
Synthesis of 5,6,7,8-tetrahydro-1,6-naphthyridines and related heterocycles by cobalt-catalyzed [2 + 2 + 2] cyclizations.通过钴催化的[2 + 2 + 2]环化反应合成5,6,7,8-四氢-1,6-萘啶及相关杂环化合物。
Org Lett. 2007 Feb 1;9(3):393-6. doi: 10.1021/ol0625280.
7
Synthesis of 2-aryl/heteroaryloxazolines from nitriles under metal- and catalyst-free conditions and evaluation of their antioxidant activities.在无金属和催化剂条件下，由腈合成 2-芳基/杂芳基恶唑啉及其抗氧化活性评价。
J Org Chem. 2014 Sep 19;79(18):8668-77. doi: 10.1021/jo501430p. Epub 2014 Sep 9.
8
Tandem oxidation of allylic and benzylic alcohols to esters catalyzed by N-heterocyclic carbenes.N-杂环卡宾催化烯丙醇和苄醇串联氧化为酯
Org Lett. 2007 Jan 18;9(2):371-4. doi: 10.1021/ol062940f.
9
Copper N-Heterocyclic Carbene Complexes As Active Catalysts for the Synthesis of 2-Substituted Oxazolines from Nitriles and Aminoalcohols.铜氮杂环卡宾配合物作为由腈类和氨基醇合成2-取代恶唑啉的活性催化剂
J Org Chem. 2015 Oct 16;80(20):9910-4. doi: 10.1021/acs.joc.5b01382. Epub 2015 Oct 1.
10
Copper-catalyzed benzylic C(sp(3))-H alkoxylation of heterocyclic compounds.铜催化杂环化合物的苄基C(sp(3))-H烷氧基化反应
Org Biomol Chem. 2014 Apr 28;12(16):2528-32. doi: 10.1039/c4ob00215f.
引用本文的文献
1
Eureka Moments Shared by Chemists. Hints at Enhancing One's Own Creativity (and Even One's Joy).化学家们分享的顿悟时刻。暗示着提升个人创造力（甚至是个人幸福感）。
ACS Cent Sci. 2024 Oct 31;10(11):1980-1996. doi: 10.1021/acscentsci.4c00802. eCollection 2024 Nov 27.
2
Construction of -Aryl-Substituted Pyrrolidines by Successive Reductive Amination of Diketones via Transfer Hydrogenation.通过转移氢化法对二酮进行连续还原胺化反应构建 -芳基取代的吡咯烷
Molecules. 2024 May 30;29(11):2565. doi: 10.3390/molecules29112565.
3
Recent Advances in Synthetic Routes to Azacycles.最近在合成氮杂环的路线方面的进展。
Molecules. 2023 Mar 17;28(6):2737. doi: 10.3390/molecules28062737.
4
Rhodium-catalysed tetradehydro-Diels-Alder reactions of enediynes a rhodium-stabilized cyclic allene.铑催化的烯二炔的十四脱氢-狄尔斯-阿尔德反应——一种铑稳定的环状丙二烯。
Chem Sci. 2020 Sep 4;11(40):10945-10950. doi: 10.1039/d0sc04390g.
5
Testing the limits of radical-anionic CH-amination: a 10-million-fold decrease in basicity opens a new path to hydroxyisoindolines a mixed C-N/C-O-forming cascade.测试自由基阴离子碳氢胺化反应的极限：碱度降低1000万倍为羟基异吲哚啉开辟了一条新途径——一种C-N/C-O形成的混合串联反应。
Chem Sci. 2020 Feb 21;11(25):6539-6555. doi: 10.1039/c9sc06511c.
6
Total Syntheses of Lyconadins: Finding Efficiency and Diversity.莱康那丁的全合成：探寻效率与多样性
Synlett. 2014;25(15):2093-2098. doi: 10.1055/s-0034-1378319.
本文引用的文献
1
Cyclobutene ring-opening of bicyclo[4.2.0]octa-1,6-dienes: access to CF3-substituted 5,6,7,8-tetrahydro-1,7-naphthyridines.[4.2.0]辛二烯的环丁烯开环反应：制备 CF3 取代的 5,6,7,8-四氢-1,7-萘啶。
J Org Chem. 2012 Oct 5;77(19):8518-26. doi: 10.1021/jo301501r. Epub 2012 Sep 14.
2
Stereospecific intramolecular C-H amination of 1-aza-2-azoniaallene salts.1-氮杂-2-氮杂环丙烯盐的立体专一性分子内 C-H 胺化反应。
J Am Chem Soc. 2012 Jun 20;134(24):9890-3. doi: 10.1021/ja303054c. Epub 2012 Jun 8.
3
Total synthesis of Akuammiline alkaloid (-)-vincorine via intramolecular oxidative coupling.通过分子内氧化偶联全合成阿枯米林生物碱（-）-长春碱。
J Am Chem Soc. 2012 Jun 6;134(22):9126-9. doi: 10.1021/ja303602f. Epub 2012 May 29.
4
Rhodium-Catalyzed C-H Amination - An Enabling Method for Chemical Synthesis.铑催化的C-H胺化反应——化学合成的一种有效方法。
Org Process Res Dev. 2011 Jul 15;15(4):758-762. doi: 10.1021/op200046v.
5
Catalytic dehydrogenative cross-coupling: forming carbon-carbon bonds by oxidizing two carbon-hydrogen bonds.催化脱氢交叉偶联：通过氧化两个碳氢键形成碳-碳键。
Chem Rev. 2011 Mar 9;111(3):1215-92. doi: 10.1021/cr100280d.
6
Experimental characterization and computational study of unique C,N-chelated lithium dianions.独特的 C，N-螯合二锂阴离子的实验特性和计算研究。
J Am Chem Soc. 2010 Sep 29;132(38):13212-3. doi: 10.1021/ja106852n.
7
Total synthesis and absolute stereochemical assignment of (-)-communesin F.(-)-communesin F 的全合成与绝对立体化学构型确定。
J Am Chem Soc. 2010 Sep 29;132(38):13226-8. doi: 10.1021/ja106739g.
8
Total synthesis of (+/-)- and (-)-actinophyllic acid.(+/-)-和(-)-actinophyllic 酸的全合成。
J Am Chem Soc. 2010 Apr 7;132(13):4894-906. doi: 10.1021/ja100178u.
9
Pd(II)-catalyzed amination of C-H bonds using single-electron or two-electron oxidants.钯（II）催化的碳氢键胺化反应，使用单电子或双电子氧化剂。
J Am Chem Soc. 2009 Aug 12;131(31):10806-7. doi: 10.1021/ja904709b.
10
Total synthesis of (+)-lyconadin A and related compounds via oxidative C-N bond formation.通过氧化C-N键形成实现（+）-lyconadin A及相关化合物的全合成。
J Am Chem Soc. 2009 Aug 12;131(31):11187-94. doi: 10.1021/ja903868n.
Zotero 插件