US Geological Survey, Colorado Water Science Center, Denver Federal Center, Denver, CO 80225, USA.
Environ Monit Assess. 2013 Sep;185(9):7081-95. doi: 10.1007/s10661-013-3086-6. Epub 2013 Jan 25.
This study evaluates the effect of emission reductions at two coal-fired power plants in northwestern Colorado on a nearby wilderness area. Control equipment was installed at both plants during 1999-2004 to reduce SO2 and NOx emissions. One challenge was separating the effects of local from regional emissions, which also declined during the study period. The long-term datasets examined confirm that emission reductions had a beneficial effect on air and water quality in the wilderness. Despite a 75 % reduction in SO2 emissions, sulfate aerosols measured in the wilderness decreased by only 20 %. Because the site is relatively close to the power plants (<75 km), the slow rate of conversion of SO2 to sulfate, particularly under conditions of low relative humidity, might account for this less than one-to-one response. On the clearest days, emissions controls appeared to improve visibility by about 1 deciview, which is a small but perceptible improvement. On the haziest days, however, there was little improvement perhaps reflecting the dominance of regional haze and other components of visibility degradation particularly organic carbon and dust. Sulfate and acidity in atmospheric deposition decreased by 50 % near the southern end of the wilderness of which 60 % was attributed to power plant controls and the remainder to reductions in regional sources. Lake water sulfate responded rapidly to trends in deposition declining at 28 lakes monitored in and near the wilderness. Although no change in the acid-base status was observed, few of the lakes appear to be at risk from chronic or episodic acidification.
本研究评估了科罗拉多州西北部两座燃煤电厂减排对附近荒野地区的影响。1999 年至 2004 年期间,两座电厂都安装了控制设备以减少 SO2 和 NOx 的排放。一个挑战是将当地和区域排放的影响分开,而在研究期间,区域排放也有所减少。所检查的长期数据集证实,减排对荒野地区的空气和水质产生了有益影响。尽管 SO2 排放量减少了 75%,但在荒野中测量的硫酸盐气溶胶仅减少了 20%。由于该地点离电厂较近(<75 公里),SO2 向硫酸盐转化的速度较慢,特别是在相对湿度较低的情况下,这可能导致这种不成比例的反应。在最晴朗的日子里,排放控制措施似乎使能见度提高了约 1 个视度,这是一个很小但可以察觉到的改善。然而,在最浑浊的日子里,几乎没有改善,这也许反映了区域雾霾和其他能见度下降成分(特别是有机碳和灰尘)的主导地位。荒野南端大气沉积中的硫酸盐和酸度减少了 50%,其中 60%归因于电厂控制,其余归因于区域来源的减少。在荒野内和附近监测的 28 个湖泊中,湖水硫酸盐迅速响应沉积趋势,呈下降趋势。尽管没有观察到酸碱状态的变化,但很少有湖泊似乎面临慢性或间歇性酸化的风险。