Institute of Intelligent Machines, Chinese Academy of Sciences, Hefei 230031, China.
Analyst. 2013 Mar 21;138(6):1858-64. doi: 10.1039/c3an36683a. Epub 2013 Feb 4.
A gold monolayer film and cysteine layer-by-layer self-assemble onto modified glasses, and through the use of optical waveguide spectroscopy (OWGS) and a dynamic SERS technique for the first time to study the dynamic generation process of the Meisenheimer complex between TNT and cysteine. This strategy can detect TNT down to 1 nM with high sensitivity and selectivity.
金单层膜和半胱氨酸通过层层自组装到修饰的玻璃上,并首次使用光波导光谱(OWGS)和动态 SERS 技术研究 TNT 与半胱氨酸之间的 Meisenheimer 复合物的动态生成过程。该策略可以高灵敏度和选择性地检测低至 1 nM 的 TNT。