一类新型高溶剂化变色二氰合铼（I）二亚胺配合物——合成、光物理和光催化。
A new class of highly solvatochromic dicyano rhenate(I) diimine complexes--synthesis, photophysics and photocatalysis.
机构信息
Department of Biology and Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong, China.
出版信息
Chem Commun (Camb). 2013 Mar 21;49(23):2311-3. doi: 10.1039/c3cc39189b.
PMID:23396368
Abstract
A new class of dicarbonyl dicyano rhenate(I) diimine complexes, cis,trans-Re(CO)(2)(CN)(2)(N-N), with highly environmentally sensitive MLCT absorption and emission properties was synthesised and characterised. Preliminary experiments revealed that these complexes are active photocatalysts for CO(2) reduction.
摘要
一类新型的二羰基二氰合铼（I）二亚胺配合物，顺式，反式-[Re(CO)(2)(CN)(2)(N-N)]-，具有高度环境敏感的 MLCT 吸收和发射性质，已被合成和表征。初步实验表明，这些配合物是 CO(2)还原的有效光催化剂。
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