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质子交换膜燃料电池垫片组件的性能与降解——综述

Properties and degradation of the gasket component of a proton exchange membrane fuel cell--a review.

作者信息

Basuli Utpal, Jose Jobin, Lee Ran Hee, Yoo Yong Hwan, Jeong Kwang-Un, Ahn Jou-Hyeon, Nah Changwoon

机构信息

Energy Harvesting WCU Research Team, Department of Polymer-Nano Science and Technology, Chonbuk National University, Jeonju 561-756, Republic of Korea.

出版信息

J Nanosci Nanotechnol. 2012 Oct;12(10):7641-57. doi: 10.1166/jnn.2012.6627.

Abstract

Proton exchange membrane (PEM) fuel cell stack requires gaskets and seals in each cell to keep the reactant gases within their respective regions. Gasket performance is integral to the successful long-term operation of a fuel cell stack. This review focuses on properties, performance and degradation mechanisms of the different polymer gasket materials used in PEM fuel cell under normal operating conditions. The different degradation mechanisms and their corresponding representative mitigation strategies are also presented here. Summary of various properties of elastomers and their advantages and disadvantages in fuel cell'environment are presented. By considering the level of chemical degradation, mechanical properties and cost effectiveness, it can be proposed that EPDM is one of the best choices for gasket material in PEM fuel cell. Finally, the challenges that remain in using rubber component as in PEM fuel cell, as well as the prospects for exploiting them in the future are discussed.

摘要

质子交换膜(PEM)燃料电池堆在每个电池中都需要垫片和密封件,以将反应气体保持在各自的区域内。垫片性能对于燃料电池堆的长期成功运行至关重要。本综述重点关注PEM燃料电池在正常运行条件下使用的不同聚合物垫片材料的性能、性能和降解机制。本文还介绍了不同的降解机制及其相应的代表性缓解策略。介绍了弹性体的各种性能及其在燃料电池环境中的优缺点。通过考虑化学降解程度、机械性能和成本效益,可以提出三元乙丙橡胶(EPDM)是PEM燃料电池垫片材料的最佳选择之一。最后,讨论了在PEM燃料电池中使用橡胶部件仍然存在的挑战以及未来开发它们的前景。

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