双（咪唑）（5,10,15,20-四苯基卟啉）铁（III）双（顺式-1,2-二氰基乙烯二硫醇）铜（III）四氢呋喃溶剂化物的结构
Structure of bis(imidazole)(5,10,15,20-tetraphenylporphinato)iron(III) bis(cis-1,2-dicyanoethylenedithiolato)cuprate(III) Tetrakis(tetrahydrofuran) solvate.
作者信息
Serr B R, Headford C E, Elliott C M, Anderson O P
机构信息
Department of Chemistry, Colorado State University, Fort Collins 80523.
出版信息
Acta Crystallogr C. 1990 Mar 15;46 ( Pt 3):500-2. doi: 10.1107/s0108270189010620.
[Fe(C44H28N4)(C3H4N2)2][Cu(C4N2S2)2].-4C4H8O, Mr = 1437.1, triclinic, P1-, a = 10.012 (4), b = 11.604 (6), c = 15.802 (7) A, alpha = 71.42 (4), beta = 87.12 (3), gamma = 78.45 (4) degrees, V = 1704 (1) A3, Z = 1, Dx = 1.40 g cm-3, lambda(Mo K alpha) = 0.7107 A, mu = 6.9 cm-1, F(000) = 747, T = 143 K, R = 0.063 for 4935 unique observed reflections. Fe is six-coordinate, Fe--N(porphinato) (av.) = 1.99 (2), Fe--N(imidazole) = 1.981 (3) A; Cu--S (av.) = 2.172 (8) A.
[Fe(C₄₄H₂₈N₄)(C₃H₄N₂)₂][Cu(C₄N₂S₂)₂]·4C₄H₈O，Mr = 1437.1，三斜晶系，P1-，a = 10.012(4)，b = 11.604(6)，c = 15.802(7)Å，α = 71.42(4)，β = 87.12(3)，γ = 78.45(4)°，V = 1704(1)ų，Z = 1，Dx = 1.40 g cm⁻³，λ(Mo Kα) = 0.7107 Å，μ = 6.9 cm⁻¹，F(000) = 747，T = 143 K，对4935个独立观测反射，R = 0.063。铁为六配位，Fe--N(卟啉)(平均) = 1.99(2)，Fe--N(咪唑) = 1.981(3)Å；Cu--S(平均) = 2.172(8)Å。
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