醇促进的开环炔烃复分解聚合反应。
Alcohol-promoted ring-opening alkyne metathesis polymerization.
机构信息
Department of Chemistry, Columbia University, 3000 Broadway, New York, NY 10027, USA.
出版信息
Angew Chem Int Ed Engl. 2013 Apr 22;52(17):4591-4. doi: 10.1002/anie.201300758. Epub 2013 Apr 8.
PMID:23568783
Abstract
Alcohol is the answer! An inactive, air-stable, dimeric molybdenum alkylidyne complex is activated toward ring-opening alkyne metathesis polymerization (ROAMP) by the addition of methanol. The ROAMP is compatible with water and phenol-containing substrates and with the in situ photochemical generation of alkyne monomers from cyclopropenones.
摘要
酒精是答案！通过添加甲醇，一种非活性、空气稳定的二聚态钼碳化物配合物被激活，可用于开环炔烃复分解聚合（ROAMP）。ROAMP 与水和含酚底物以及环丙烯酮原位光化学生成炔烃单体兼容。
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