通过外延生长和配体取代的程序化结晶来杂交多孔配位聚合物晶体。
Programmed crystallization via epitaxial growth and ligand replacement towards hybridizing porous coordination polymer crystals.
机构信息
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto, 615-8510, Japan.
出版信息
Dalton Trans. 2013 Dec 7;42(45):15868-72. doi: 10.1039/c3dt50679g. Epub 2013 Apr 23.
PMID:23612878
Abstract
Hybridized porous coordination polymers (PCPs) are synthesized through epitaxial growth or ligand replacement. Whereas epitaxial growth on the core crystal leads to a sandwich type PCP, ligand replacement near the surface of core crystal results in a core-shell type PCP.
摘要
杂化多孔配位聚合物（PCPs）是通过外延生长或配体取代合成的。在外延生长过程中，核心晶体上的生长导致三明治型 PCP，而核心晶体表面附近的配体取代则导致核壳型 PCP。
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