Sasagawa Kosuke, Sakamoto Rei, Hijikata Daichi, Yonezawa Noriyuki, Okamoto Akiko
Department of Organic and Polymer Materials Chemistry, Tokyo University of Agriculture & Technology, Koganei, Tokyo 184-8588, Japan.
Acta Crystallogr Sect E Struct Rep Online. 2013 Apr 5;69(Pt 5):o651. doi: 10.1107/S1600536813008581. Print 2013 May 1.
The title mol-ecule, C30H28O6, possesses crystallographically imposed twofold symmetry, with two central C atoms in the naphthalene unit lying on the rotation axis along [001]. The 4-eth-oxy-benzoyl groups at the peri positions of the naphthalene ring system are disordered over two sets of sites with occupancies of 0.769 (4) and 0.231 (4). They are directed in opposite directions from the naphthalene plane (anti orientation). For the major component, the dihedral angle between the aroyl benzene ring and the naphthalene ring system is 75.62 (13)° [minor component 75.5 (4)°], and that between the aroyl benzene rings is 32.58 (15)°. In the crystal, mol-ecules are linked via C-H⋯O and C-H⋯π inter-actions, forming a three-dimensional network.