铀酰离子与刚性芳香羧酸根的配位作用及其配合物的结构表征。

Uranyl ion coordination with rigid aromatic carboxylates and structural characterization of their complexes.

机构信息

The Skaggs Institute for Chemical Biology and Department of Chemistry, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla CA, 92037, USA.

出版信息

Chem Commun (Camb). 2013 Jul 21;49(57):6379-81. doi: 10.1039/c3cc43358g.

DOI:10.1039/c3cc43358g

PMID:23752768

Abstract

Uranyl complexes of rigid aromatic carboxylates were synthesized and their solid-state structures characterized by X-ray crystallography. The new ligands create cavities lined with endohedral functions to encapsulate the uranyl ion.

摘要

合成了刚性芳香羧酸根的铀酰配合物，并通过 X 射线晶体学对其固态结构进行了表征。这些新的配体形成了具有内禀功能的内腔，以包裹铀酰离子。