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基于原位膦氧化反应或氧化膦配体的新型膦氧化物供体超分子配位化合物。

New class of phosphine oxide donor-based supramolecular coordination complexes from an in situ phosphine oxidation reaction or phosphine oxide ligands.

机构信息

Department of Chemistry, University of Delhi , Delhi 110 007, India.

出版信息

Inorg Chem. 2013 Sep 16;52(18):10217-9. doi: 10.1021/ic401257w. Epub 2013 Aug 28.

DOI:10.1021/ic401257w
PMID:23984852
Abstract

A one-pot, multicomponent, coordination-driven self-assembly approach was used to synthesize the first examples of neutral bridging phosphine oxide donor-based supramolecular coordination complexes. The complexes were self-assembled from a fac-Re(CO)3 acceptor, an anionic bridging O donor, and a neutral soft phosphine or hard phosphine oxide donor.

摘要

采用一锅多组分、配位驱动的自组装方法合成了首例中性桥联膦氧供体的超分子配位化合物。该配合物由 fac-Re(CO)3 受体、阴离子桥联 O 供体和中性软膦或硬膦氧供体自组装而成。

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