Laboratory of Organometallics, Catalysis and Ordered Materials, State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, China.
Chem Soc Rev. 2013 Dec 21;42(24):9304-32. doi: 10.1039/c3cs60244c. Epub 2013 Sep 18.
In the midst of the global climate change phenomenon, mainly caused by fossil fuel burning to provide energy for our daily life and discharge of CO2 into the atmosphere, biogas is one of the important renewable energy sources that can be upgraded and applied as a fuel source for energy in daily life. The advantages of the production of hybrid materials, metal-organic framework (MOF) adsorbents, expected for the biogas upgrading, rely on the bulk separation of CO2 under near-ambient conditions. This review highlights the challenges for MOF adsorbents, which have the greatest upgrading abilities for biogas via selective passage of methane. The key factors improving the ideal MOF materials for these high CO2 capture and selectivity uses for biogas upgrading to produce bio-methane and reduce fossil-fuel CO2 emission will be discussed.
在全球气候变化现象中,主要是由于燃烧化石燃料为我们的日常生活提供能源并将二氧化碳排放到大气中造成的,沼气是一种重要的可再生能源,可以升级并应用于日常生活中的能源燃料。生产混合材料、金属有机骨架(MOF)吸附剂的优势在于可以在接近环境的条件下分离 CO2。这篇综述强调了 MOF 吸附剂的挑战,它们通过甲烷的选择性传递对沼气具有最大的升级能力。将讨论提高理想 MOF 材料的关键因素,这些材料用于沼气升级以生产生物甲烷和减少化石燃料 CO2 排放具有高 CO2 捕获和选择性。