Zaumseil Peter, Kozlowski Grzegorz, Yamamoto Yuji, Schubert Markus Andreas, Schroeder Thomas
IHP , Im Technologiepark 25, Frankfurt (Oder), 15236, Germany.
J Appl Crystallogr. 2013 Aug 1;46(Pt 4):868-873. doi: 10.1107/S0021889813003518. Epub 2013 Jun 7.
On the way to integrate lattice mismatched semiconductors on Si(001), the Ge/Si heterosystem was used as a case study for the concept of compliant substrate effects that offer the vision to be able to integrate defect-free alternative semiconductor structures on Si. Ge nanoclusters were selectively grown by chemical vapour deposition on Si nano-islands on silicon-on-insulator (SOI) substrates. The strain states of Ge clusters and Si islands were measured by grazing-incidence diffraction using a laboratory-based X-ray diffraction technique. A tensile strain of up to 0.5% was detected in the Si islands after direct Ge deposition. Using a thin (∼10 nm) SiGe buffer layer between Si and Ge the tensile strain increases to 1.8%. Transmission electron microscopy studies confirm the absence of a regular grid of misfit dislocations in such structures. This clear experimental evidence for the compliance of Si nano-islands on SOI substrates opens a new integration concept that is not only limited to Ge but also extendable to semiconductors like III-V and II-VI materials.
在将晶格失配半导体集成到Si(001)的过程中,Ge/Si异质系统被用作一个案例研究,以探讨柔性衬底效应的概念,该效应为在Si上集成无缺陷的替代半导体结构提供了愿景。通过化学气相沉积在绝缘体上硅(SOI)衬底上的Si纳米岛上选择性生长Ge纳米团簇。使用基于实验室的X射线衍射技术,通过掠入射衍射测量Ge团簇和Si岛的应变状态。在直接沉积Ge后,在Si岛中检测到高达0.5%的拉伸应变。在Si和Ge之间使用薄(约10nm)的SiGe缓冲层,拉伸应变增加到1.8%。透射电子显微镜研究证实,此类结构中不存在失配位错的规则网格。SOI衬底上Si纳米岛柔性的这一明确实验证据开启了一种新的集成概念,该概念不仅限于Ge,还可扩展到III-V和II-VI等半导体材料。