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基于 1,8-萘酰亚胺衍生物的高选择性比色和比率荧光化学传感器用于检测氟离子。

A highly selective colorimetric and ratiometric fluorescent chemodosimeter for detection of fluoride ions based on 1,8-naphthalimide derivatives.

机构信息

College of Biotechnology and Pharmaceutical Engineering, Nanjing University of Technology, No. 200, North Zhongshan Road, Nanjing 210009, China.

出版信息

Spectrochim Acta A Mol Biomol Spectrosc. 2014 Jan 24;118:239-43. doi: 10.1016/j.saa.2013.08.100. Epub 2013 Aug 31.

Abstract

A high selective colorimetric and ratiometric fluorescent probe based on 4-hydroxy-1, 8-naphthalimide was designed and synthesized to detect fluoride ions (F(-)). The sensing behavior of this probe was studied by UV-visible and fluorescence spectroscopy. The probe displays an 110 nm red-shift of fluorescence emission and the color changes from colorless to yellow by virtue of the strong affinity of F(-) toward silicon which can act as a new visual sensor for F(-).

摘要

设计并合成了一种基于 4-羟基-1,8-萘酰亚胺的高选择性比色和比率荧光探针,用于检测氟离子(F(-))。通过紫外可见吸收光谱和荧光光谱研究了该探针的传感行为。探针通过氟离子(F(-))与硅的强亲和力,显示出荧光发射的 110nm 红移和颜色从无色变为黄色,可作为 F(-)的新型可视化传感器。

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