采用流动电解色谱法研究 Md3+/Md2+ 还原电势的测量。
Measurement of the Md3+/Md2+ reduction potential studied with flow electrolytic chromatography.
机构信息
Japan Atomic Energy Agency (JAEA), Tokai, Ibaraki 319-1195, Japan.
出版信息
Inorg Chem. 2013 Nov 4;52(21):12311-3. doi: 10.1021/ic401571h. Epub 2013 Oct 11.
PMID:24116851
Abstract
The reduction behavior of mendelevium (Md) was studied using a flow electrolytic chromatography apparatus. By application of the appropriate potentials on the chromatography column, the more stable Md(3+) is reduced to Md(2+). The reduction potential of the Md(3+) + e(-) → Md(2+) couple was determined to be -0.16 ± 0.05 V versus a normal hydrogen electrode.
摘要
采用流动电解色谱仪研究了镆（Md）的还原行为。通过在色谱柱上施加适当的电势，更稳定的 Md(3+)被还原为 Md(2+)。Md(3+) + e(-) → Md(2+) 电对的还原电位被确定为相对于标准氢电极的-0.16 ± 0.05 V。
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