Department of Chemical Engineering, School of Environmental and Chemical Engineering, Shanghai University , Shangda Road 99, Shanghai, P. R. China , 200444.
ACS Appl Mater Interfaces. 2013 Nov 27;5(22):12073-82. doi: 10.1021/am403905x. Epub 2013 Nov 7.
Reduced graphene oxide (RGO) nanosheet-supported SnS2 nanosheets are prepared by a one-step microwave-assisted technique. These SnS2 nanosheets are linked with each other and dispersed uniformly on RGO surface. The SnS2-RGO sheet-on-sheet nanostructure exhibits good electrochemical performances as an anode material for lithium ion batteries. It shows larger-than-theoretical reversible capacities at 0.1 C and excellent high-rate capability at 1 C and 5 C. The composite is also for the first time identified as an excellent visible light-driven catalyst of rhodamine B and phenol with high degradation efficiencies. The removal rates of rhodamine B and phenol are 100 and 83.2%, respectively, for the SnS2-RGO composite, whereas these values are only 64.8 and 51.5% for pristine SnS2 after the same irradiation times. The outstanding electrochemical or photocatalytic performances of the composite have been attributed to the complementary effect of RGO and SnS2 in the perfect sheet-on-sheet composition nanostructure.
通过一步微波辅助技术制备了还原氧化石墨烯(RGO)纳米片负载的 SnS2 纳米片。这些 SnS2 纳米片相互连接并均匀分散在 RGO 表面。SnS2-RGO 片层结构纳米结构作为锂离子电池的阳极材料表现出良好的电化学性能。在 0.1 C 时具有比理论值更大的可逆容量,在 1 C 和 5 C 时具有优异的高倍率性能。该复合材料还首次被鉴定为罗丹明 B 和苯酚的高效可见光驱动催化剂,具有很高的降解效率。对于 SnS2-RGO 复合材料,罗丹明 B 和苯酚的去除率分别为 100%和 83.2%,而在相同的照射时间后,原始 SnS2 的去除率仅为 64.8%和 51.5%。该复合材料具有出色的电化学或光催化性能,这归因于 RGO 和 SnS2 在完美的片层结构纳米结构中的互补效应。