偕三乙醇胺的铼（I）配合物捕集 CO2。
CO2 capture by a rhenium(I) complex with the aid of triethanolamine.
机构信息
Department of Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology , 2-12-1-NE1, O-okayama, Meguro-ku, Tokyo 152-8550, Japan.
出版信息
J Am Chem Soc. 2013 Nov 13;135(45):16825-8. doi: 10.1021/ja409271s. Epub 2013 Oct 29.
A rhenium(I) tricarbonyl diimine complex with a N,N-dimethylformamide ligand captures one CO2 molecule in the presence of triethanolamine (TEOA), giving fac-[Re(I)(bpy)(CO)3{R2N-CH2CH2O-COO}] (bpy = 2,2'-bipyridine, R = CH2CH2OH). This could be a predominant complex in various photocatalytic CO2 reduction reactions using Re(I)(N^N)(CO)3X (N^N = diimine ligand; X = monodentate ligand; n = 0, 1) type complexes in the presence of TEOA.
一种铼（I）三羰基二亚胺配合物与 N,N-二甲基甲酰胺配体在三乙醇胺 (TEOA) 的存在下捕获一个 CO2 分子，得到 fac-[Re(I)(bpy)(CO)3{R2N-CH2CH2O-COO}]（bpy = 2,2'-联吡啶，R = CH2CH2OH）。这可能是在存在 TEOA 的情况下使用 Re(I)(N^N)(CO)3X（N^N = 二亚胺配体；X = 单齿配体；n = 0,1）类型配合物进行各种光催化 CO2 还原反应中的主要配合物。
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