TERI University, 10 Institutional Area, Vasant Kunj, New Delhi 110 070, India; TERI, Darbari Seth Block, India Habitat Centre, New Delhi 110 003, India.
Bioresour Technol. 2013 Dec;150:172-80. doi: 10.1016/j.biortech.2013.09.069. Epub 2013 Sep 27.
An anoxic biocathode was developed using sulfate-reducing bacteria (SRB) consortium on activated carbon fabric (ACF) and the effect of stainless steel (SS) mesh as additional current collector was investigated. Improved performance of biocathode was observed with SS mesh leading to nearly five folds increase in power density (from 4.79 to 23.11 mW/m(2)) and threefolds increase in current density (from 75 to 250 mA/m(2)). Enhanced redox currents and lower Tafel slopes observed from cyclic voltammograms of ACF with SS mesh indicated the positive role of uniform electron collecting points. Differential pulse voltammetry technique was employed as an additional tool to assess the redox carriers involved in bioelectrochemical reactions. SRB biocathode was also tested for reduction of volatile fatty acids (VFA) present in the fermentation effluent stream and the results indicated the possibility of integration of this system with anaerobic fermentation for efficient product recovery.
采用附着在活性碳纤维(ACF)上的硫酸盐还原菌(SRB)联合体开发了一种缺氧生物阴极,并研究了不锈钢(SS)网作为附加集流器的效果。在 SS 网的作用下,生物阴极的性能得到了改善,其功率密度(从 4.79 增加到 23.11 mW/m(2))增加了近五倍,电流密度(从 75 增加到 250 mA/m(2))增加了三倍。从带有 SS 网的 ACF 的循环伏安图中观察到增强的氧化还原电流和更低的塔菲尔斜率表明均匀电子收集点的积极作用。差分脉冲伏安法技术被用作评估生物电化学反应中涉及的氧化还原载体的附加工具。还对 SRB 生物阴极进行了测试,以还原发酵废水中存在的挥发性脂肪酸(VFA),结果表明该系统与厌氧发酵集成以进行有效产物回收的可能性。