Department of Environmental Sciences, Central University of Himachal Pradesh, Dharamshala, Himachal Pradesh, 176215, India,
Environ Sci Pollut Res Int. 2014 Feb;21(4):2414-36. doi: 10.1007/s11356-013-2337-y. Epub 2013 Nov 27.
Pollution resulting from hazardous glass (HG) is widespread across the globe, both in terms of quantity and associated health risks. In waste cathode ray tube (CRT) and fluorescent lamp glass, mercury and lead are present as the major pollutants. The current review discusses the issues related to quantity and associated risk from the pollutant present in HG and proposes the chemical, biological, thermal, hybrid, and nanotechniques for its management. The hybrid is one of the upcoming research models involving the compatible combination of two or more techniques for better and efficient remediation. Thermal mercury desorption starts at 100 °C but for efficient removal, the temperature should be >460 °C. Involvement of solar energy for this purpose makes the research more viable and ecofriendly. Nanoparticles such as Fe, Se, Cu, Ni, Zn, Ag, and WS2 alone or with its formulation can immobilize heavy metals present in HG by involving a redox mechanism. Straight-line equation from year-wise sale can provide future sale data in comparison with lifespan which gives future pollutant approximation. Waste compact fluorescent lamps units projected for the year 2015 is 9,300,000,000 units and can emit nearly 9,300 kg of mercury. On the other hand, CRT monitors have been continuously replaced by more improved versions like liquid crystal display and plasma display panel resulting in the production of more waste. Worldwide CRT production was 83,300,000 units in 2002 and can approximately release 83,000 metric tons of lead.
全球范围内都存在危险玻璃(HG)造成的污染,无论是在数量还是相关健康风险方面。在废阴极射线管(CRT)和荧光灯玻璃中,汞和铅是主要污染物。本综述讨论了 HG 中污染物的数量和相关风险问题,并提出了化学、生物、热、混合和纳米技术来管理它们。混合是一种新兴的研究模式,涉及两种或更多技术的兼容组合,以实现更好和更有效的修复。热汞解吸在 100°C 时开始,但为了有效去除,温度应>460°C。为此目的利用太阳能使研究更可行和环保。纳米颗粒如 Fe、Se、Cu、Ni、Zn、Ag 和 WS2 单独或与其制剂一起可以通过涉及氧化还原机制来固定 HG 中存在的重金属。逐年销售的直线方程可以与使用寿命进行比较,提供未来的销售数据,从而估算未来的污染物。预计 2015 年将有 93 亿支紧凑型荧光灯报废,可排放近 9300 公斤汞。另一方面,CRT 显示器不断被更先进的版本(如液晶显示器和等离子显示器)取代,导致产生更多的废物。2002 年全球 CRT 产量为 8330 万支,大约可释放 83000 吨铅。