Suppr超能文献

使用三维质谱成像的回顾性溅射深度剖析。

Retrospective sputter depth profiling using 3D mass spectral imaging.

作者信息

Zheng Leiliang, Wucher Andreas, Winograd Nicholas

机构信息

Department of Chemistry, Pennsylvania State University, University Park, PA 16802, USA.

Faculty of Physics, University Duisburg-Essen, 47048 Duisburg, Germany.

出版信息

Surf Interface Anal. 2011 Feb;43(1-2). doi: 10.1002/sia.3509.

Abstract

A molecular multilayer stack composed of alternating Langmuir-Blodgett films was analyzed by ToF-SIMS imaging in combination with intermediate sputter erosion using a focused C cluster ion beam. From the resulting dataset, depth profiles of any desired lateral portion of the analyzed field-of-view can be extracted in retrospect, allowing the influence of the gating area on the apparent depth resolution to be assessed. In a similar way, the observed degradation of depth resolution with increasing depth of the analyzed interface can be analyzed in order to determine the 'intrinsic' depth resolution of the method.

摘要

通过使用聚焦的C簇离子束,结合中间溅射侵蚀的飞行时间二次离子质谱成像(ToF-SIMS成像),对由交替的朗缪尔-布洛杰特(Langmuir-Blodgett)膜组成的分子多层堆叠进行了分析。从所得数据集中,可以事后提取分析视场中任何所需横向部分的深度剖面,从而能够评估门控区域对表观深度分辨率的影响。以类似的方式,可以分析随着被分析界面深度增加而观察到的深度分辨率下降情况,以便确定该方法的“固有”深度分辨率。

相似文献

1
Retrospective sputter depth profiling using 3D mass spectral imaging.
Surf Interface Anal. 2011 Feb;43(1-2). doi: 10.1002/sia.3509.
2
3D ToF-SIMS imaging of polymer multilayer films using argon cluster sputter depth profiling.
ACS Appl Mater Interfaces. 2015 Feb 4;7(4):2654-9. doi: 10.1021/am507663v. Epub 2015 Jan 20.
4
Fundamental studies of molecular depth profiling and 3D imaging using Langmuir-Blodgett films as a model.
Appl Surf Sci. 2008 Dec 15;255(4):816-818. doi: 10.1016/j.apsusc.2008.05.250.
5
Depth profiling of metal overlayers on organic substrates with cluster SIMS.
Anal Chem. 2013 Nov 5;85(21):10565-72. doi: 10.1021/ac402658r. Epub 2013 Oct 10.
6
Large O Cluster Ions as Sputter Beam for ToF-SIMS Depth Profiling of Alkali Metals in Thin SiO Films.
Anal Chem. 2017 Feb 21;89(4):2377-2382. doi: 10.1021/acs.analchem.6b04222. Epub 2017 Feb 9.
8
10
Three-dimensional depth profiling of molecular structures.
Anal Bioanal Chem. 2009 Apr;393(8):1835-42. doi: 10.1007/s00216-008-2596-5. Epub 2009 Jan 20.

本文引用的文献

1
Fundamental studies of molecular depth profiling and 3D imaging using Langmuir-Blodgett films as a model.
Appl Surf Sci. 2008 Dec 15;255(4):816-818. doi: 10.1016/j.apsusc.2008.05.250.
2
Depth resolution during C60+ profiling of multilayer molecular films.
Anal Chem. 2008 Oct 1;80(19):7363-71. doi: 10.1021/ac801056f. Epub 2008 Sep 6.
3
Chemically alternating Langmuir-Blodgett thin films as a model for molecular depth profiling by mass spectrometry.
J Am Soc Mass Spectrom. 2008 Jan;19(1):96-102. doi: 10.1016/j.jasms.2007.10.020.
4
Depth profiling brain tissue sections with a 40 keV C60+ primary ion beam.
Anal Chem. 2008 Mar 15;80(6):2125-32. doi: 10.1021/ac702127q. Epub 2008 Feb 16.
5
TOF-SIMS 3D biomolecular imaging of Xenopus laevis oocytes using buckminsterfullerene (C60) primary ions.
Anal Chem. 2007 Mar 15;79(6):2199-206. doi: 10.1021/ac061370u. Epub 2007 Feb 16.
6
Depth profiling of peptide films with TOF-SIMS and a C60 probe.
Anal Chem. 2005 Jun 1;77(11):3651-9. doi: 10.1021/ac048131w.
7
Depth profiling of Langmuir-Blodgett films with a buckminsterfullerene probe.
Anal Chem. 2004 Nov 15;76(22):6651-8. doi: 10.1021/ac0492665.
9
Performance characteristics of a chemical imaging time-of-flight mass spectrometer.
Rapid Commun Mass Spectrom. 1998;12(18):1246-52. doi: 10.1002/(SICI)1097-0231(19980930)12:18<1246::AID-RCM316>3.0.CO;2-C.

文献AI研究员

20分钟写一篇综述,助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型,支持多种主流文档格式。

立即体验