Department of Lipid Science and Traditional Foods, Central Food Technological and Research Institute (Council of Scientific and Industrial Research), Mysore, 570020 India.
J Food Sci Technol. 2014 Feb;51(2):315-21. doi: 10.1007/s13197-011-0492-z. Epub 2011 Aug 24.
Speciality plastic fats with no trans fatty acids suitable for use in bakery and as vanaspati substitute were prepared by interesterification of blends of palm stearin (PSt) with sal and mango fats using Lipozyme TLIM lipase as catalyst. The blends containing PSt/sal or PSt/mango showed short melting range and hence are not suitable as bakery shortenings. Lipase catalysed interesterification extended the plasticity or melting range of all the blends. The blends containing higher proportion of PSt with sal fat (50/50) were harder having high solids at and above body temperature and hence cannot be used as bakery shortenings. The blends with PSt/sal (30-40/60-70) after interesterification showed melting profiles similar to those of commercial hydrogenated bakery fats. Similarly, the blends containing PSt/mango (30-40/60-70) after interesterification also showed melting profiles similar to those of commercial hydrogenated shortenings. The slip melting point and solidification characteristics also confirm the plastic nature of these samples. The improvement in plasticity after interesterification is due to formation of higher melting as well as lower melting triglycerides during lipase catalysed interesterification.
采用脂肪酶 TLIM 作为催化剂,通过棕榈硬脂(PSt)与沙律油和芒果脂的混合物进行酯交换反应,制备了不含反式脂肪酸的特殊塑性脂肪,可用于烘焙和替代凡纳滨虾油。含有 PSt/沙律油或 PSt/芒果脂的混合物具有较短的融解范围,因此不适合用作烘焙起酥油。脂肪酶催化的酯交换反应扩展了所有混合物的可塑性或融解范围。含有较高比例 PSt 和沙律油(50/50)的混合物较硬,在体温及以上时具有较高的固体含量,因此不能用作烘焙起酥油。经过酯交换后的 PSt/沙律油(30-40/60-70)混合物的融解曲线与商业氢化烘焙脂肪相似。同样,经过酯交换后的 PSt/芒果脂(30-40/60-70)混合物的融解曲线也与商业氢化起酥油相似。滑动熔点和凝固特性也证实了这些样品的塑性性质。酯交换后塑性的提高是由于在脂肪酶催化的酯交换过程中形成了更高和更低熔点的三酸甘油酯。