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[再生废聚甲基丙烯酸甲酯(PMMA)行业挥发性有机化合物(VOCs)排放特征分析]

[Characterization of volatile organic compounds (VOCs) emission from recycled waste polymethyl methacrylate (PMMA) industry].

作者信息

Wang Zhe-Ming, Xu Zhi-Rong, Ye Hong-Yu, Xu Ming-Zhu, Wang Xiao-Xing

出版信息

Huan Jing Ke Xue. 2013 Dec;34(12):4571-6.

Abstract

In the present study, the main source and characteristics of volatile organic compounds (VOCs) released from recycled waste polymethyl methacrylate (PMMA) in Zhejiang province was analyzed quantitatively and qualitatively. Based on those results, the internationally recognized evaluation model of health risk assessment was adopted in the preliminary assessment of the health risk of those VOCs. The results showed that methanol (MeOH) and methyl methacrylate (MMA) were the main pollutants. Emission from part of enterprises exceeded the national standards in MeOH and MMA, especially for fugitive emissions of odor concentration. Moreover, health risk value of fugitive emissions was very low and did not cause harm to human health. Additionally, to better accelerate industrial upgrading and environment pollution treatment, the emission limits of MeOH, MMA and odor concentration were suggested and the values of existing/new (fugitive emission) limitations were 45/30 (0.5) mg x m(-3), 30/25 (0.5) mg x m(-3), and 1000/800 (20), respectively.

摘要

在本研究中,对浙江省回收废聚甲基丙烯酸甲酯(PMMA)释放的挥发性有机化合物(VOCs)的主要来源和特征进行了定量和定性分析。基于这些结果,在对这些VOCs的健康风险进行初步评估时采用了国际认可的健康风险评估模型。结果表明,甲醇(MeOH)和甲基丙烯酸甲酯(MMA)是主要污染物。部分企业的甲醇和甲基丙烯酸甲酯排放量超过国家标准,尤其是恶臭浓度的无组织排放。此外,无组织排放的健康风险值非常低,不会对人体健康造成危害。此外,为了更好地推动产业升级和环境污染治理,建议了甲醇、甲基丙烯酸甲酯和恶臭浓度的排放限值,现有/新建(无组织排放)限值分别为45/30(0.5)mg·m⁻³、30/25(0.5)mg·m⁻³和1000/800(20)。

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