Environ Technol. 2014 Mar-Apr;35(5-8):984-92. doi: 10.1080/09593330.2013.857725.
We investigated the feasibility of using ordered mesoporous carbon (OMC) for bromate removal from water. Batch experiments were performed to study the influence of various experimental parameters such as the effect of contact time, adsorbent dosage, initial bromate concentration, temperature, pH and effect of competing anions on bromate removal by OMC. The adsorption kinetics indicates that the uptake rate ofbromate was rapid at the beginning: 85% adsorption was completed in 1 h and equilibrium was achieved within 3 h. The sorption process was well described with pseudo-second-order kinetics. The maximum adsorption capacity of OMC for bromate removal was 17.6 mg g(-1) at 298 K. The adsorption data fit the Freundlich model well. The amount of bromate removed was found to be proportional to the influent bromate concentration. The effects of competing anions and solution pH (3-11) were negligible. These limited data suggest that OMC can be effectively utilized for bromate removal from drinking water.
我们研究了有序介孔碳(OMC)用于去除水中溴酸盐的可行性。进行了批量实验,研究了各种实验参数的影响,例如接触时间、吸附剂剂量、初始溴酸盐浓度、温度、pH 值以及竞争阴离子对 OMC 去除溴酸盐的影响。吸附动力学表明,溴酸盐的吸收速率在开始时很快:在 1 小时内完成了 85%的吸附,在 3 小时内达到平衡。吸附过程很好地符合拟二级动力学。OMC 对溴酸盐去除的最大吸附容量在 298 K 时为 17.6 mg g(-1)。吸附数据很好地符合 Freundlich 模型。去除的溴酸盐量与进水溴酸盐浓度成正比。竞争阴离子和溶液 pH 值(3-11)的影响可以忽略不计。这些有限的数据表明,OMC 可有效用于去除饮用水中的溴酸盐。