PMMH, CNRS UMR 7636, ESPCI ParisTech, Université Paris 6, Université Paris 7, 10, rue Vauquelin, Paris 75005, France.
1] PMMH, CNRS UMR 7636, ESPCI ParisTech, Université Paris 6, Université Paris 7, 10, rue Vauquelin, Paris 75005, France [2] Ecole Normale Supérieure de Lyon, CNRS UMR 5672, 46 allée d'Italie, Lyon 69007, France.
Nat Commun. 2014 Mar 25;5:3474. doi: 10.1038/ncomms4474.
When periodically driven, a number of markedly different systems (colloids, droplets, grains, flux lines) have revealed a transition from a reversible to an irreversible dynamics that hardly depends on the very nature of the interacting objects. Yet, no clear structural signature has been found for this collective self-organization. Here, we demonstrate an archetypal Loschmidt-echo experiment involving thousands of droplets that interact in a reversible fashion via a viscous fluid. First, we show that periodically driven microfluidic emulsions self-organize and geometrically protect their macroscopic reversibility. Self-organization is not merely dynamical: it has a clear structural signature. Second, we show that, above a maximal shaking amplitude, structural order and reversibility are lost simultaneously through a first-order non-equilibrium phase transition. We account for this discontinuous transition in terms of a memory-loss process. Finally, we suggest potential applications of microfluidic echo as a robust tool to tailor colloidal self-assembly at large scales.
当周期性驱动时,许多明显不同的系统(胶体、液滴、颗粒、通量线)显示出从可逆动力学向不可逆动力学的转变,而这几乎与相互作用的物体的性质无关。然而,对于这种集体自组织,还没有找到明确的结构特征。在这里,我们展示了一个涉及数千个液滴的典型 Loschmidt 回波实验,这些液滴通过粘性流体以可逆的方式相互作用。首先,我们表明周期性驱动的微流乳液会自组织并在几何上保护其宏观可逆性。自组织不仅仅是动态的:它有一个明确的结构特征。其次,我们表明,在最大振动幅度以上,结构有序性和可逆性会通过一级非平衡相变同时丧失。我们根据记忆损失过程来解释这种不连续的转变。最后,我们提出了微流回波作为一种在大尺度上定制胶体自组装的强大工具的潜在应用。