含有桥连硝酰基的二亚硝酰基铁配合物[Fe₄(μ₃-S)₂(μ₂-NO)₂(NO)₆]²⁻：桥连和末端NO配位配体的¹⁵N (NO) NMR分析
The dinitrosyliron complex [Fe₄(μ₃-S)₂(μ₂-NO)₂(NO)₆]²⁻ containing bridging nitroxyls: ¹⁵N (NO) NMR analysis of the bridging and terminal NO-coordinate ligands.
作者信息
Yeh Shih-Wey, Tsou Chih-Chin, Liaw Wen-Feng
机构信息
Department of Chemistry, National Tsing Hua University, Hsinchu 30013, Taiwan.
出版信息
Dalton Trans. 2014 Jun 28;43(24):9022-5. doi: 10.1039/c4dt00450g.
PMID:24821662
Abstract
The fluxional terminal and semibridging NO-coordinate ligands of DNIC Fe4(μ3-S)2(μ2-NO)2(NO)6, a precursor of Roussin's black salt (RBS), are characterized by IR ν(NO), (15)N (NO) NMR and single-crystal X-ray diffraction.
摘要
二亚硝酰基二硫代四铁酸根阴离子Fe4(μ3-S)2(μ2-NO)2(NO)6是鲁辛黑盐（RBS）的前体，其具有易变的端基和半桥连NO配位配体，通过红外ν(NO)、(15)N (NO)核磁共振和单晶X射线衍射对其进行了表征。
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