单线态氧介导的azaspiracids 中双螺环缩酮的合成。
Singlet oxygen-mediated synthesis of bis-spiroketals found in azaspiracids.
机构信息
Department of Chemistry, University of Crete , Vasilika Vouton, 71003 Iraklion, Crete, Greece.
出版信息
Org Lett. 2014 Jun 6;16(11):3150-3. doi: 10.1021/ol501301w. Epub 2014 May 28.
PMID:24869923
Abstract
Conversion of a simple furan into the ABCD-ring skeleton of the azaspiracids via a singlet oxygen-initiated one-pot process has been accomplished.
摘要
通过单重态氧引发的一锅法，成功地将一个简单的呋喃转化为氮杂螺环酸的 ABCD 环骨架。
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