迈向动态薄膜中芳基碳-氮键的形成
Towards aryl C-N bond formation in dynamic thin films.
作者信息
Gandy Michael N, Raston Colin L, Stubbs Keith A
机构信息
School of Chemistry and Biochemistry, The University of Western Australia, Crawley, WA 6009, Australia.
出版信息
Org Biomol Chem. 2014 Jul 14;12(26):4594-7. doi: 10.1039/c4ob00926f.
PMID:24887640
Abstract
C-N bond forming reactions are important in organic chemistry. A thin film microfluidic vortex fluidic device (VFD) operating under confined mode affords N-aryl compounds from 2-chloropyrazine and the corresponding amine, without the need for a transition metal catalyst.
摘要
碳氮键形成反应在有机化学中很重要。一种在受限模式下运行的薄膜微流控涡旋流体装置（VFD），无需过渡金属催化剂，就能从2-氯吡嗪和相应的胺制备出N-芳基化合物。
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