Two pentasilahousanes fused together.

作者信息

Tsurusaki Akihiro, Koganezono Makoto, Otsuka Kyohei, Ishida Shintaro, Kyushin Soichiro

机构信息

Division of Molecular Science, Graduate School of Science and Technology, Gunma University, Kiryu, Gunma 376-8515 (Japan).

出版信息

Chemistry. 2014 Jul 21;20(30):9263-6. doi: 10.1002/chem.201403375. Epub 2014 Jul 7.

DOI:10.1002/chem.201403375

PMID:25043525

Abstract

The organosilicon cluster 1 with two pentasilahousanes fused together was synthesized by the reduction of 1,1,3-trichlorocyclotetrasilane. This reaction involves dimerization and rearrangement of the silicon skeleton. The structure and properties of 1 were studied by X-ray crystallographic and spectroscopic analyses.

摘要