（N-膦亚胺基）钴催化的硼氢化反应：烯烃异构化实现末端选择性。
(N-phosphinoamidinate)cobalt-catalyzed hydroboration: alkene isomerization affords terminal selectivity.
作者信息
Ruddy Adam J, Sydora Orson L, Small Brooke L, Stradiotto Mark, Turculet Laura
机构信息
Department of Chemistry, Dalhousie University, 6274 Coburg Road, P.O. Box 15000, Halifax, Nova Scotia B3H 4R2 (Canada).
出版信息
Chemistry. 2014 Oct 20;20(43):13918-22. doi: 10.1002/chem.201403945. Epub 2014 Sep 3.
PMID:25187346
Abstract
Herein we establish the utility of a three-coordinate (N-phosphinoamidinate)cobalt(amido) pre-catalyst that is capable of effecting challenging alkene isomerization/hydroboration processes at room temperature, leading to the selective terminal addition of the boron group.
摘要
在此，我们确立了一种三配位（N-膦基脒基）钴（酰胺基）预催化剂的效用，该预催化剂能够在室温下实现具有挑战性的烯烃异构化/硼氢化反应，从而实现硼基团的选择性末端加成。
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