Suppr超能文献

Crystal structure of (Z)-2,3-di-chloro-1,4-bis-(4-meth-oxy-phen-yl)but-2-ene-1,4-dione.

作者信息

Tittal Ram K, Kumar Satish, Ram R N

机构信息

Department of Chemistry, Indian Institute of Technology Delhi, Hauzkhas, New Delhi 110 016, India.

Department of Chemistry, St Stephen's College, University Enclave, Delhi 110 007, India.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2014 Aug 23;70(Pt 9):o1049-50. doi: 10.1107/S1600536814018790. eCollection 2014 Sep 1.

Abstract

The title compound, C18H14Cl2O4, adopts a Z conformation around the cental C=C bond. The two aromatic rings of the mol-ecule are nearly perpendicular to each other, with a dihedral angle between of 86.22 (14)°. The meth-oxy substituents lie close to the plane of the attached benzene rings. The C(ar)-C(ar)-O-C(Me) torsion angles are -2.4 (7) and 7.5 (6)°. Weak C-H⋯O inter-actions link the mol-ecules forming a three-dimensional network. The crystal packing also displays short [3.160 (3) Å] Cl⋯O halogen-bonding contacts between mol-ecules related by the screw axis. The structure exhibits disorder of one carbonyl O atom with a refined occupancy ratio of 0.21 (6):0.79 (6).

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7956/4186131/d47b7411303a/e-70-o1049-fig1.jpg

文献AI研究员

20分钟写一篇综述,助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型,支持多种主流文档格式。

立即体验