反式水合-（高氯酸根-κO）双-（丙烷-1,3-二胺-κ(2) N,N'）高氯酸铜（II）的晶体结构
Crystal structure of trans-aqua-(perchlorato-κO)bis-(propane-1,3-di-amine-κ(2) N,N')copper(II) perchlorate.
作者信息
Govindaraj J, Rajkumar K, Ganeshraja A S, Anbalagan K, SubbiahPandi A
机构信息
Department of Physics, Pachaiyappa's College for Men, Kanchipuram 631 501, India.
Department of Chemistry, Pondicherry University, Pondicherry 605 014, India.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2014 Oct 31;70(Pt 11):438-40. doi: 10.1107/S1600536814023496. eCollection 2014 Nov 1.
In the title compound, [Cu(ClO4)(C3H10N2)2(H2O)]ClO4, the Cu(II) atom has a distorted octa-hedral coordination sphere and is coordinated by the N atoms of two propane-1,3-di-amine ligands in the equatorial plane. The axial positions are occupied by a water O atom and an O atom of a disordered perchlorate anion [occupancy ratio 0.631 (9):0.369 (9)]. In the crystal, the various components are linked via O-H⋯O, N-H⋯O and C-H⋯O hydrogen bonds, forming sheets lying parallel to (001).
在标题化合物[Cu(ClO₄)(C₃H₁₀N₂)₂(H₂O)]ClO₄中，Cu(II)原子具有扭曲的八面体配位环境，在赤道平面上由两个1,3 - 丙二胺配体的N原子配位。轴向位置由一个水分子的O原子和一个无序高氯酸根阴离子的O原子占据[占有率为0.631 (9):0.369 (9)]。在晶体中，各种组分通过O—H⋯O、N—H⋯O和C—H⋯O氢键相连，形成平行于(001)的片层。
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