Wang Dong, Niu Jian, Wang Zhenggong, Jin Jian
Nano-Bionics Division and i-Lab, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences , Suzhou, Jiangsu 215123, People's Republic of China.
Langmuir. 2015 Feb 10;31(5):1670-4. doi: 10.1021/acs.langmuir.5b00053. Epub 2015 Jan 28.
Oil/water separation has been a worldwide subject because of increasing release of oil-containing wastewater as well as several marine oil spills. The phase-selective organogelators (PSOGs) are thought to offer a potential and effective implement for addressing this issue. An ideal PSOG for oil adsorption must fulfill some requirements involving effective gelation, easy synthesis, low cost, and recyclable for reuse. However, beyond those, the ability of gelation for a broad-range oil phase without selectivity is also important. However, most of the reported PSOGs have limitation in this respect thus far. In this paper, a new class of saturated 1-monoglyceride-derived organogelators can efficiently uptake almost all of the common fuel oils from water and gelate organic solvents with extremely low minimum gelation concentration (MGC). In addition, the oils in the gel and gelator molecules can be recovered quantitatively through simple vacuum distillation.
由于含油废水排放日益增多以及多起海洋石油泄漏事件,油水分离已成为一个全球性课题。相选择性有机凝胶剂(PSOGs)被认为是解决这一问题的一种潜在且有效的手段。用于油吸附的理想PSOG必须满足一些要求,包括有效凝胶化、易于合成、成本低以及可回收再利用。然而,除此之外,无选择性地对宽范围油相进行凝胶化的能力也很重要。然而,到目前为止,大多数已报道的PSOG在这方面都存在局限性。本文中,一类新型的饱和甘油单酯衍生有机凝胶剂能够高效地从水中摄取几乎所有常见燃料油,并以极低的最低凝胶化浓度(MGC)使有机溶剂凝胶化。此外,通过简单的减压蒸馏可以定量回收凝胶中的油和凝胶剂分子。