Krasnovsky A A, Kozlov A S
Biofizika. 2014 Mar-Apr;59(2):250-7.
Generation of singlet oxygen upon excitation of oxygen molecules by infrared diode lasers has been studied in organic media (carbon tetrachloride and acetone) saturated by air under normal pressure and temperature. A new approach to analysis of the experimental data has been developed taking into account a degree of overlapping of the spectral bands of oxygen and laser radiation. Optical density, molar absorption coefficient and the cross section of light absorption were determined for the main absorption maxima of O2 at 765 and 1273 nm. The results are compared with the data of previous studies. A significance of the obtained results for elucidation of photophysics and photochemistry of oxygen molecules and investigation of biological action of laser radiation is discussed.
在常压和常温下,研究了红外二极管激光器激发氧气分子在空气饱和的有机介质(四氯化碳和丙酮)中产生单线态氧的情况。考虑到氧气和激光辐射光谱带的重叠程度,开发了一种分析实验数据的新方法。测定了O2在765和1273nm处主要吸收峰的光密度、摩尔吸收系数和光吸收截面。将结果与先前研究的数据进行了比较。讨论了所得结果对阐明氧分子的光物理和光化学以及研究激光辐射的生物作用的意义。