碱金属介导的二甲胺硼烷（Me2NH·BH3）脱氢偶联反应
Alkali metal-mediated dehydrocoupling of Me2NH·BH3.
作者信息
Bellham Peter, Hill Michael S, Kociok-Köhn Gabriele
机构信息
Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, UK.
出版信息
Dalton Trans. 2015 Jul 21;44(27):12078-81. doi: 10.1039/c5dt00178a.
PMID:25789721
Abstract
Bis(trimethylsilyl)amide derivatives of the group 1 elements (Li, Na, K) are competent pre-catalysts for the dehydrocoupling of Me2NH·BH3 via the formation of intermediates containing H3BNMe2BH2Me2N anions.
摘要
第1族元素（锂、钠、钾）的双（三甲基硅基）酰胺衍生物是通过形成含有H3BNMe2BH2Me2N阴离子的中间体来催化Me2NH·BH3脱氢偶联反应的有效预催化剂。
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