Zeng Hua, Li Yiran, Xu Fengyu, Jiang Hao, Zhang Weimin
a State Key Laboratory Breeding Base of Nuclear Resources and Environment , East China Institute of Technology , Nanchang , Jiangxi , People's Republic of China.
Environ Technol. 2015;36(19):2495-501. doi: 10.1080/09593330.2015.1036130. Epub 2015 May 7.
Several studies have focused on pollutant removal by magnetic seeding and high-gradient superconducting magnetic separation (HGSMS). However, few works reported the application of HGSMS for treating non-magnetic pollutants by an industrial large-scale system. The feasibility of turbidity removal by a 600 mm bore superconducting magnetic separation system was evaluated in this study. The processing parameters were evaluated by using a 102 mm bore superconducting magnetic separation system that was equipped with the same magnetic separation chamber that was used in the 600 mm bore system. The double-canister system was used to process water pollutants. Analytical grade magnetite was used as a magnetic seed and the turbidity of the simulated raw water was approximately 110 NTU, and the effects of polyaluminum chloride (PAC) and magnetic seeds on turbidity removal were evaluated. The use of more PAC and magnetic seeds had few advantages for the HGSMS at doses greater than 8 and 50 mg/l, respectively. A magnetic intensity of 5.0 T was beneficial for HGSMS, and increasing the flow rate through the steel wool matrix decreased the turbidity removal efficiency. In the breakthrough experiments, 90% of the turbidity was removed when 100 column volumes were not reached. The processing capacity of the 600 mm bore industry-scale superconducting magnetic separator for turbidity treatment was approximately 78.0 m(3)/h or 65.5 × 10(4) m(3)/a. The processing cost per ton of water for the 600 mm bore system was 0.1 $/t. Thus, the HGSMS separator could be used in the following special circumstances: (1) when adequate space is not available for traditional water treatment equipment, especially the sedimentation tank, and (2) when decentralized sewage treatment HGSMS systems are easier to transport and install.
多项研究聚焦于通过磁种和高梯度超导磁选(HGSMS)去除污染物。然而,鲜有研究报道HGSMS在工业大规模系统中处理非磁性污染物的应用。本研究评估了内径600 mm超导磁选系统去除浊度的可行性。通过使用内径102 mm的超导磁选系统评估工艺参数,该系统配备了与内径600 mm系统相同的磁选室。采用双罐系统处理水中污染物。使用分析纯磁铁矿作为磁种,模拟原水的浊度约为110 NTU,并评估了聚合氯化铝(PAC)和磁种对浊度去除的影响。当PAC和磁种的投加量分别大于8 mg/l和50 mg/l时,增加其用量对HGSMS去除浊度的效果提升不大。5.0 T的磁场强度有利于HGSMS,增加通过钢丝棉基质的流速会降低浊度去除效率。在穿透实验中,未达到100个柱体积时,90%的浊度已被去除。内径600 mm工业规模超导磁选机处理浊度的能力约为78.0 m³/h或65.5×10⁴ m³/a。内径600 mm系统每吨水的处理成本为0.1美元/t。因此,HGSMS分离器可用于以下特殊情况:(1)当没有足够空间安装传统水处理设备,尤其是沉淀池时;(2)当分散污水处理时,HGSMS系统更易于运输和安装。