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[油青色翡翠的矿物学与颜色]

[Mineralogy and colosation of oil-green jadeite jade].

作者信息

Yin Ke, Tian Jian, Ma Yu-bo, Wu Yu, Wang Yang

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2014 Dec;34(12):3323-6.

Abstract

Mineralogy and coloration of oil-green jadeite jade were investigated using X-Ray diffraction (XRD), Fourier transform infrared absorption spectroscopy (FTIR) and scanning electron microscopy (SEM). XRD results show that "flesh" of oil-green jadeite jade is mainly composed of relatively pure jadeite, whereas the "skin" of which is dominated by jadeite, chlorite and chrysotile. The mineral constituents revealed by FTIR are fairly consistent with XRD. Three typical adsorption peaks of ~2956, ~2919 and ~2850 cm(-1) related to organic matters occurred in both "flesh" and "skin" of oil-green jadeite jade. Jadeite in "flesh" exhibits an obvious columnar growth and has a better crystallinity than that of "skin". However, jadeite in "skin" is richer in magnesium than that of "flesh", suggesting an intense water-rock reaction of jadeite in "skin". Chrysotile just occurs in "skin" of oil-green jadeite jade, and it presents a curved crystal plane. Flaky chlorite was detected in both cracks of "flesh" and "skin", which might be the main cause of coloration of oil-green jadeite jade. Chlorite, formed in the reducing water-rock reaction, would adsorb or wrap a certain amount of organic matters, resulting in the occurrence of the characteristic adsorptions of oil-green jadeite jade.

摘要

采用X射线衍射(XRD)、傅里叶变换红外吸收光谱(FTIR)和扫描电子显微镜(SEM)对油青玉的矿物学特征和颜色成因进行了研究。XRD结果表明,油青玉的“肉”主要由相对纯净的硬玉组成,而其“皮”则以硬玉、绿泥石和蛇纹石为主。FTIR揭示的矿物成分与XRD结果相当一致。在油青玉的“肉”和“皮”中均出现了与有机物相关的2956、2919和~2850 cm(-1)三个典型吸附峰。“肉”中的硬玉呈现出明显的柱状生长,结晶度比“皮”中的硬玉更好。然而,“皮”中的硬玉比“肉”中的硬玉富含更多的镁,这表明“皮”中的硬玉发生了强烈的水岩反应。蛇纹石仅出现在油青玉的“皮”中,且呈现出弯曲的晶面。在“肉”和“皮”的裂隙中均检测到片状绿泥石,这可能是油青玉颜色形成的主要原因。在还原水岩反应中形成的绿泥石会吸附或包裹一定量的有机物,从而导致油青玉出现特征性吸附。

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