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医用棉的功能化:直接掺入纳米银颗粒。

Functionalization of medical cotton by direct incorporation of silver nanoparticles.

机构信息

Textile Research Division, National Research Centre, Dokki, Cairo 12311, Egypt.

Chemistry Department, Faculty of Science, Helwan University, Ain-Helwan, Cairo 11795, Egypt.

出版信息

Int J Biol Macromol. 2015 Jul;78:249-56. doi: 10.1016/j.ijbiomac.2015.04.018. Epub 2015 Apr 20.

Abstract

Medical cotton is usually used to clean skin, pack wounds and in other surgical tasks. Such important usages make imparting the antibacterial property to medical cotton is so essential research. The current research focuses on functionalization of medical cotton by direct incorporation of silver nanoparticles (AgNPs) in two-step process namely, pre-alkalization followed by sorption. Decorative color and antibacterial action were accomplished for medical cotton after in situ incorporation of AgNPs without using any other external reducing agent. AgNPs were produced due to the reduction action of alcoholic and aldehydic groups of cotton's skeletal blocks. Cotton fibers were acquired a decorative color attributed to surface plasmon resonance of AgNPs. The treated cotton was characterized by using electron microscope. Results showed that Ag(0) with size distribution of 0-160 nm was formed in the cotton fibers and their size majority (70%) was less than 80 nm. The reduction of Ag(+) to Ag(0) was confirmed by measuring the carboxylic and aldehydic contents. The treated cotton exhibited excellent antibacterial action at low silver contents. The absorbency of cotton was not affected by treatment. The produced medical cotton could be used to safe cleaning of wounds without getting any microbial infections.

摘要

医用棉通常用于清洁皮肤、包扎伤口和其他外科手术。如此重要的用途使得赋予医用棉抗菌性能成为如此重要的研究。目前的研究集中在通过直接将银纳米粒子(AgNPs)掺入两步法即预碱化后吸附来对医用棉进行功能化。通过在原位掺入 AgNPs,无需使用任何其他外部还原剂,即可为医用棉赋予装饰性颜色和抗菌作用。AgNPs 的产生是由于棉花骨架块的醇和醛基的还原作用。棉纤维获得了归因于 AgNPs 表面等离子体共振的装饰性颜色。用电子显微镜对处理过的棉花进行了表征。结果表明,Ag(0)的尺寸分布在 0-160nm 之间形成在棉纤维中,其大小多数(70%)小于 80nm。通过测量羧酸和醛基含量证实了 Ag(+)到 Ag(0)的还原。在低银含量下,处理过的棉花表现出优异的抗菌作用。棉花的吸湿性不受处理的影响。所生产的医用棉可用于安全清洁伤口,而不会受到任何微生物感染。

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