Russo John, Tanaka Hajime
Department of Fundamental Engineering, Institute of Industrial Science, University of Tokyo, Tokyo 153-8505, Japan
Proc Natl Acad Sci U S A. 2015 Jun 2;112(22):6920-4. doi: 10.1073/pnas.1501911112. Epub 2015 May 18.
The possible role of growing static order in the dynamical slowing down toward the glass transition has recently attracted considerable attention. On the basis of random first-order transition theory, a new method to measure the static correlation length of amorphous order, called "point-to-set" (PTS) length, has been proposed and used to show that the dynamic length grows much faster than the static length. Here, we study the nature of the PTS length, using a polydisperse hard-disk system, which is a model that is known to exhibit a growing hexatic order upon densification. We show that the PTS correlation length is decoupled from the steeper increase of the correlation length of hexatic order and dynamic heterogeneity, while closely mirroring the decay length of two-body density correlations. Our results thus provide a clear example that other forms of order can play an important role in the slowing down of the dynamics, casting a serious doubt on the order-agnostic nature of the PTS length and its relevance to slow dynamics, provided that a polydisperse hard-disk system is a typical glass former.
在向玻璃化转变的动力学减速过程中,不断增长的静态有序结构可能发挥的作用最近引起了相当大的关注。基于随机一阶转变理论,一种测量非晶态有序结构静态关联长度的新方法——“点到集”(PTS)长度被提出,并用于表明动态长度的增长比静态长度快得多。在此,我们使用多分散硬球系统研究PTS长度的性质,该系统是一个已知在致密化时会呈现出不断增长的六次对称性有序结构的模型。我们表明,PTS关联长度与六次对称性有序结构和动态不均匀性的关联长度的急剧增加解耦,同时紧密反映两体密度关联的衰减长度。因此,我们的结果提供了一个明确的例子,即其他形式的有序结构可以在动力学减速中发挥重要作用,这对PTS长度与慢动力学无关的无序性本质提出了严重质疑,前提是多分散硬球系统是一种典型的玻璃形成体。