在MoO(x)/SiO2催化剂上异佛尔酮催化转化为喷气燃料馏程芳烃
Catalytic conversion of isophorone to jet-fuel range aromatic hydrocarbons over a MoO(x)/SiO2 catalyst.
作者信息
Chen Fang, Li Ning, Wang Wentao, Wang Aiqin, Cong Yu, Wang Xiaodong, Zhang Tao
机构信息
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China.
出版信息
Chem Commun (Camb). 2015 Jul 28;51(59):11876-9. doi: 10.1039/c5cc03087k.
PMID:26110372
Abstract
For the first time, jet fuel range C8-C9 aromatic hydrocarbons were synthesized in high carbon yield (∼80%) by the catalytic conversion of isophorone over MoO(x)/SiO2 at atmospheric pressure. A possible reaction pathway was proposed according to the control experiments and the intermediates generated during the reaction.
摘要
首次在常压下通过异佛尔酮在MoO(x)/SiO2上的催化转化以高碳产率（约80%）合成了喷气燃料范围的C8 - C9芳烃。根据对照实验和反应过程中生成的中间体提出了一条可能的反应途径。
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