"Stripping" the carbon atom of methyl halide by a cationic holmium complex: a gas-phase study.
作者信息
Zhou Shaodong, Schlangen Maria, Li Jilai, Wu Xiao-Nan, Schwarz Helmut
机构信息
Institut für Chemie, Technische Universität Berlin, Straße des 17. Juni 135, 10623 Berlin (Germany).
出版信息
Chemistry. 2015 Oct 5;21(41):14305-8. doi: 10.1002/chem.201502183. Epub 2015 Aug 25.
PMID:26331900
Abstract
Mechanistic aspects of an unusual reaction of HoC6 H4 S with CH3 X (X=Cl, Br, I) have been investigated using Fourier-transform ion cyclotron resonance mass spectrometry combined with density functional theory (DFT) calculations. In this thermal process, all four bonds of the methyl halides are cleaved.
摘要
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