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自组装单分子层:局部纳米多孔缺陷的星状结晶开裂(Adv. Mater. 33/2015)。

Self-Assembled Monolayers: Star-Shaped Crystallographic Cracking of Localized Nanoporous Defects (Adv. Mater. 33/2015).

机构信息

Institute for Materials Research (IMO), Hasselt University and Associated Lab IMEC Division IMOMEC, Wetenschapspark 1, 3590, Diepenbeek, Belgium.

Max-Planck-Institut für Eisenforschung GmbH, Max-Planck-Straße 1, D-40237, Düsseldorf, Germany.

出版信息

Adv Mater. 2015 Sep 2;27(33):4947. doi: 10.1002/adma.201570223.

Abstract

On page 4877, F. U. Renner, A. Bashir, M. Valtiner, and co-workers describe a star-like dealloying corrosion morphology that appears during the localized attack of smooth well-prepared Cu-Au surfaces. The surfaces are initially protected by thiol or selenol inhibitior films. Localized dealloying of Cu-Au produces nanoporous gold under stress and crystallographic cracks - thereby opening a new approach combining surface science with nanoscale mechanical testing.

摘要

第 4877 页,F. U. Renner、A. Bashir、M. Valtiner 及同事描述了一种在光滑预处理的 Cu-Au 表面局部腐蚀时出现的类星状脱合金腐蚀形态。这些表面最初由硫醇或硒醇抑制剂薄膜保护。Cu-Au 的局部脱合金在应力下产生纳米多孔金和结晶裂纹-从而开辟了将表面科学与纳米力学测试相结合的新途径。

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