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燃烧合成法制备掺(Er³⁺,Yb³⁺)Y₂O₃纳米荧光粉的光致发光性能。

Photoluminescence properties of rare-earth-doped (Er³⁺,Yb³⁺) Y₂O₃ nanophosphors by a combustion synthesis method.

机构信息

Department of Applied Physics, Shri Shankaracharya Technical Campus, Bhilai, Chhattisgarh, 490020, India.

School of Studies in Physics & Astrophysics, Pt. Ravishankar Shukla University, Raipur, Chhattisgarh, 492010, India.

出版信息

Luminescence. 2016 May;31(3):728-37. doi: 10.1002/bio.3017. Epub 2015 Sep 23.

Abstract

In this work, we report the synthesis of Y2O3:Er(3+), Y2O3:Yb(3+) and Y2O3:Er(3+),Yb(3+) nanophosphors by the combustion synthesis method using urea as fuel. The doping agents were incorporated in the form of erbium nitrate and ytterbium nitrate. X-Ray diffraction (XRD) patterns revealed that the synthesized particles have a body-centered cubic structure with space group Ia-3. The photoluminescence (PL) properties were investigated after UV and infrared irradiation at room temperature. A strong characteristic emission of Er(3+) and Yb(3+) ions was identified, and the influence of doping concentration on the PL properties was systematically studied. Energy transfer from Yb(3+) to Er(3+) ions was observed in Y2O3 nanophosphors. The obtained result may be useful in potential applications such as bioimaging.

摘要

在这项工作中,我们报告了使用尿素作为燃料的燃烧合成法合成 Y2O3:Er(3+)、Y2O3:Yb(3+) 和 Y2O3:Er(3+)、Yb(3+)纳米荧光粉。掺杂剂以硝酸铒和硝酸镱的形式掺入。X 射线衍射(XRD)图谱表明,合成的颗粒具有体心立方结构,空间群为 Ia-3。在室温下进行了紫外线和红外线辐照后,研究了光致发光(PL)性质。鉴定了 Er(3+)和 Yb(3+)离子的强特征发射,并且系统研究了掺杂浓度对 PL 性质的影响。在 Y2O3 纳米荧光粉中观察到了 Yb(3+)离子向 Er(3+)离子的能量转移。所得结果可能在生物成像等潜在应用中有用。

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