Savithri M P, Suresh M, Raghunathan R, Raja R, SubbiahPandi A
Department of Physics, Queen Mary's College (Autonomous), Chennai 600 004, India.
Department of Organic Chemistry, University of Madras, Guindy Campus, Chennai 600 025, India.
Acta Crystallogr E Crystallogr Commun. 2015 Jul 31;71(Pt 8):o627-8. doi: 10.1107/S2056989015014024. eCollection 2015 Aug 1.
In the title compound, C22H23NO2S, the inner pyrrolidine ring (A) adopts an envelope conformation with the methine C atom opposite the fused C-N bond as the flap. The thio-pyran ring (C) has a half-chair conformation and its mean plane is inclined to the fused benzene ring by 1.74 (11)°, and by 60.52 (11)° to the mean plane of pyrrolidine ring A. In the outer pyrrolidine ring (B), the C atom opposite the fused C-N bond is disordered [site-occupancy ratio = 0.427 (13):0.573 (13)] and both rings have envelope conformations, with the disordered C atom as the flap. The planes of the phenyl ring and the benzene ring of the thio-chromane unit are inclined to one another by 65.52 (14)°. In the crystal, mol-ecules are linked by a pair of C-H⋯O hydrogen bonds forming inversion dimers.
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