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Crystal structure of 2-meth-oxy-2-[(4-meth-oxy-phen-yl)sulfan-yl]-1-phenyl-ethanone.

作者信息

Caracelli Ignez, Olivato Paulo R, Traesel Henrique J, Valença Jéssica, Rodrigues Daniel N S, Tiekink Edward R T

机构信息

Departmento de Física, Universidade Federal de São Carlos, 13565-905 São Carlos, SP, Brazil.

Instituto de Química, Universidade de São Paulo, 05508-000 São Paulo, SP, Brazil.

出版信息

Acta Crystallogr E Crystallogr Commun. 2015 Aug 15;71(Pt 9):o657-8. doi: 10.1107/S2056989015014565. eCollection 2015 Sep 1.

Abstract

In the title β-thio-carbonyl compound, C16H16O3S, the adjacent meth-oxy and carbonyl O atoms are synperiplanar [the O-C-C-O torsion angle is 19.8 (4)°] and are separated by 2.582 (3) Å. The dihedral angle between the rings is 40.11 (16)°, and the meth-oxy group is coplanar with the benzene ring to which it is connected [the C-C-O-C torsion angle is 179.1 (3)°]. The most notable feature of the crystal packing is the formation of methine and methyl C-H⋯O(carbon-yl) inter-actions that lead to a supra-molecular chain with a zigzag topology along the c axis. Chains pack with no specific inter-molecular inter-actions between them.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5f21/4555440/dc65c8764161/e-71-0o657-fig1.jpg

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